#87 Which of the following ketones cannot be prepared

Which of the following ketones cannot be prepared - Organic Chemistry

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Free Chegg Question

Which of the following ketones cannot be prepared using an acetoacetic ester synthesis?

I.
II.
III.
IV
I and III
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Free Chegg Answer

This IV ketone cannot be prepared by the acetoacetic ester synthesis because in the IV structure Hydrogen does not present on alpha-carbon for deprotonation.